Microstructure Evaluation of W–20Cu Composites Produced by Liquid Phase Sintering, Liquid Infiltration and Sintering Activator Techniques

Authors

  • Hafed Ibrahim Faculty of Engineering, University of Derna, Al-Guba, Libya Author
  • Khalid Abdalla Faculty of Engineering, University of Derna, Al-Guba, Libya Author

DOI:

https://doi.org/10.58987/teqnad44

Keywords:

W-Cu composites, Microstructure, Sintering activator, Direct infiltration

Abstract

This research focused on assessing the densification and microstructural characteristics of W-20Cu sintered compacts fabricated using a hybrid approach that combines direct infiltration (DI) and liquid phase sintering (LPS). Some samples were prepared using the conventional method of liquid phase sintering to compare the results with those obtained through the copper melt infiltration (Cu-MI) technique. The sintering process was carried out in alumina tube furnace at sintering temperatures of 1150°C. In both techniques, low concentration of Ni (1wt. %) was incorporated into the W-20Cu system as a sintering accelerator. The consolidation using Cu-MI technique demonstrated its effectiveness in enhancing densification and achieving a homogeneous microstructure in the sintered compact, in contrast to the conventional LPS technique. The consolidation compact of W-20Cu-1Ni composites prepared using copper-melt infiltration techniques has high densification and the relative density exceed 96% of theoretical density. 

References

[1] N. Yang, Z. Wang, L. Chen, Y. Wang, Y. Zhu, "A new process for fabricating W-15 wt.% Cu sheet by sintering, cold rolling and re-sintering,” International Journal of Refractory Metals and Hard Materials, Vol. 28, 198-200, 2010. DOI: https://doi.org/10.1016/j.ijrmhm.2009.09.004

[2] P. Ho, Q. Li, J. Fuh, “Evaluation of W–Cu metal matrix composites produced by powder injection molding and liquid infiltration,” Materials Science and Engineering: A, Vol. 485, 657-63, 2008. DOI: https://doi.org/10.1016/j.msea.2007.10.048

[3] P. Song, J. Cheng, L. Wan, J. Zhao, Y. Wang, Y. Cai, “Preparation and characterization of Mo-15 Cu superfine powders by a gelatification-reduction process,” Journal of Alloys and compounds, Vol. 476, 226-30, 2009. DOI: https://doi.org/10.1016/j.jallcom.2008.09.097

[4] T. Schubert, B. Trindade, T. Weißgärber, B. Kieback, “Interfacial design of Cu-based composites prepared by powder metallurgy for heat sink applications,” Materials Science and Engineering: A, Vol. 475, 39-44, 2008. DOI: https://doi.org/10.1016/j.msea.2006.12.146

[5] K. Hwang, H. Huang, “The liquid phase sintering of molybdenum with Ni and Cu additions,” Materials chemistry and physics, Vol. 67, 92-100, 2001. DOI: https://doi.org/10.1016/S0254-0584(00)00425-9

[6] J. Liu, R.M. German, “Rearrangement densification in liquid-phase sintering,” Metallurgical and Materials Transactions A, Vol. 32, 3125-31, 2001. DOI: https://doi.org/10.1007/s11661-001-0187-6

[7] Y. Guo, J. Yi, S. Luo, C. Zhou, L. Chen, Y. Peng, “Fabrication of W-Cu composites by microwave infiltration,” Journal of Alloys and compounds, Vol. 492, L75-L8, 2010. DOI: https://doi.org/10.1016/j.jallcom.2009.12.011

[8] S.S. Ryu, Y.D. Kim, I.H. Moon, “Dilatometric analysis on the sintering behavior of nanocrystalline W–Cu prepared by mechanical alloying,” Journal of Alloys and Compounds, Vol. 335, 233-40, 2002 DOI: https://doi.org/10.1016/S0925-8388(01)01805-9

[9] S.B, Li, J.X. Xie, “Processing and microstructure of functionally graded W/Cu composites fabricated by multi-billet extrusion using mechanically alloyed powders,” Composites Science and Technology, Vol. 66, 2329-36, 2006. DOI: https://doi.org/10.1016/j.compscitech.2005.11.034

[10] S.H. Hong, B.K. Kim, “Fabrication of W-20 wt% Cu composite nanopowder and sintered alloy with high thermal conductivity,” Materials Letters, Vol. 57, 2761-7, 2003. DOI: https://doi.org/10.1016/S0167-577X(03)00071-5

[11] K.S. Mohammed, A. Rahmat, K.R. Ahmad, “Sintering Behavior and Microstructure Evolution of Mechanically Alloyed W–Bronze Composite Powders by Two-step Ball Milling Process,” Journal of Materials Science & Technology, Vol. 29, 59-69, 2013. DOI: https://doi.org/10.1016/j.jmst.2012.12.001

[12] J. Johnson, R. German, “Phase equilibria effects on the enhanced liquid phase sintering of tungsten-copper,” Metallurgical and Materials Transactions A, Vol. 24, 2369-77, 1993. DOI: https://doi.org/10.1007/BF02646516

[13] R.M. German, Z. Munir, “Enhanced low-temperature sintering of tungsten,” Metallurgical and Materials Transactions A, Vol. 7, 1873-7, 1976. DOI: https://doi.org/10.1007/BF02654983

[14] H. Zhang, J.R. Liu, G.H. Zhang, "Preparation and properties of W-30 wt% Cu alloy with the additions of Ni and Fe elements," Journal of Alloys and Compounds, Vol. 928, 167040, 2022. DOI: https://doi.org/10.1016/j.jallcom.2022.167040

[15] N.S. Shakunt, A. Upadhyaya. "Effect of Fe addition in W-Ni-Cu heavy alloy processed through powder metallurgy on microstructure and mechanical properties," Journal of Alloys and Compounds, Vol. 970, 172578, 2024. DOI: https://doi.org/10.1016/j.jallcom.2023.172578

[16] G. Gusmano, A. Bianco, R. Polini, P. Magistris, G. Marcheselli, “Chemical synthesis and sintering behaviour of highly dispersed W/Cu composite powders,” Journal of materials science, Vol. 36, 901-7, 2001. DOI: https://doi.org/10.1023/A:1004894900840

[17] K. Hwang, C. Yu, C. Yang, C. Yeh, L.Y. Wang, “Effects ofcontaminationonproperties of W-15Cu preparedfrom mechanically alloyed powders,” Powder metallurgy, Vol. 46, 113-6, 2003. DOI: https://doi.org/10.1179/003258903225005286

[18] J. Cai, Y. Liu, Q. Jiang, K. Feng, S. Ke, "Investigating nickel and iron as the activator in W–Mo–Cu alloy sintered via large current electric field," Journal of Materials Science. Vol. 60, 8890-8903, 2025. DOI: https://doi.org/10.1007/s10853-025-10952-0

[19] M. Ardestani, H. Rezaie, H. Arabi, H. Razavizadeh, “The effect of sintering temperature on densification of nanoscale dispersed W–20–40% wt Cu composite powders,” International Journal of Refractory Metals and Hard Materials, Vol. 27, 862-7, 2009. DOI: https://doi.org/10.1016/j.ijrmhm.2009.04.004

[20] H. Ibrahim, A. Azizan, R. Azmi, “Effects of Cobalt Addition and Temperature on Microstructure and Density of W-25Cu Composites Prepared via Liquid Infiltration,” Advanced Materials Research, Vol. 626, 430-5, 2013. DOI: https://doi.org/10.4028/www.scientific.net/AMR.626.430

[21] R. German, “Powder metallurgy science,” Metal Powder Industries Federation, Princeton, NJ. 2nd ed. Vol. 279, 1994.

[22] M.B. Uday, M.N.A. Fauzi, H. Zuhailawati, A.B. Ismail, “Thermal analysis of friction welding process in relation to the welding of YSZ-alumina composite and 6061 aluminum alloy,” Applied Surface Science, Vol. 258-8264-72, 2012. DOI: https://doi.org/10.1016/j.apsusc.2012.05.035

[23] Z.J. Zhou, J. Du, S.X. Song, Z.H. Zhong, C.C. Ge, “Microstructural characterization of W/Cu functionally graded materials produced by a one-step resistance sintering method,” Journal of Alloys and compounds, Vol. 428,146-50, 2007. DOI: https://doi.org/10.1016/j.jallcom.2006.03.073

[24] R. Jedamzik, A. Neubrand, J. Rödel, “Functionally graded materials by electrochemical processing and infiltration: application to tungsten/copper composites,” Journal of materials science, Vol. 35- 477-86, 2000. DOI: https://doi.org/10.1023/A:1004735904984

[25] J. Luo, “Liquid-like interface complexion: From activated sintering to grain boundary diagrams,” Current Opinion in Solid State and Materials Science, Vol. 12, 81-8, 2008. DOI: https://doi.org/10.1016/j.cossms.2008.12.001

[26] A.G. Hamidi, H. Arabi, S. Rastegari, “Tungsten-Copper Composites Production by Activated Sintering and Infiltration,” International Journal of Refractory Metals and Hard Materials. Vol. 29, 538-541, 2011. DOI: https://doi.org/10.1016/j.ijrmhm.2011.03.009

[27] M. Ahangarkani, S. Borgi, H. Abbaszadeh, A.A. Rahmani, K. Zangeneh-Madar, “The effect of additive and sintering mechanism on the microstructural characteristics of W–40Cu composites,” International Journal of Refractory Metals and Hard Materials, Vol. 32,39-44, 2012. DOI: https://doi.org/10.1016/j.ijrmhm.2012.01.006

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Published

2025-06-30

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How to Cite

Microstructure Evaluation of W–20Cu Composites Produced by Liquid Phase Sintering, Liquid Infiltration and Sintering Activator Techniques. (2025). Derna University Journal of Applied Sciences, 2(1), 67-75. https://doi.org/10.58987/teqnad44

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