The Effect of Co and Fe on Densification and Microstructure of W- 25wt%Cu Composites Prepared by Direct Liquid Infiltration

Authors

  • Hafed Ibrahim Author
  • Solman. M. Hassan Author

DOI:

https://doi.org/10.58987/pg1j4c55

Keywords:

Transition Elements, Densification, Liquid phase sintering, Liquid infiltration

Abstract

During this study, full-density W-25wt.% Cu composites were prepared by conventional method (liquid phase sintering and liquid infiltration). Experiments were carried out to evaluate the effect of Co and Fe additives in the range 0.3 to 3 wt.% on the densification of W- 25Cu composites. The sintering temperatures were performed at 1050oC and 1250oC for 2h under vacuum. The experimental results showed that, near full density has been achieved at 1250oC and the values of sintering density were between 97%-99% of theoretical density. In addition, the densification was depended on the concentration of transition elements and sintering temperature. The Microstructures and density were characterized using scanning electron microscope (SEM) and water displacement method, respectively. 

References

[1] Y. Guo, J. Yi, S. Luo, C. Zhou, L. Chen, Y. Peng, “Fabrication of W-Cu composites by microwave infiltration,” Journal of Alloys and Compounds, Vol.492 (1-2), 75-78, 2010. DOI: https://doi.org/10.1016/j.jallcom.2009.12.011

[2] R. German, “Powder metallurgy science,” Metal Powder Industries Federation, Princeton, NJ. 1994.

[3] W. Wang, KS Hwang, “The effect of tungsten particle size on the processing and properties of infiltrated W-Cu compacts,” Metallurgical and Materials Transactions A, Vol.29(5), 1509-1516,1998. DOI: https://doi.org/10.1007/s11661-998-0366-9

[4] J. Cheng, L. Wan, Y. Cai, J. Zhu, P. Song, J. Dong, “Fabrication of W-20 wt.% Cu alloys by powder injection molding,” Journal of Materials Processing Technology, Vol. 210(1), 137- 142, 2010. DOI: https://doi.org/10.1016/j.jmatprotec.2009.08.001

[5] Z. Zhou, YS. Kwon, “Fabrication of W– Cu composite by resistance sintering under ultra-high pressure,” Journal of Materials Processing Technology, Vol.168(1), 107-111, 2005. DOI: https://doi.org/10.1016/j.jmatprotec.2004.11.008

[6]. S.H. Hong, B.K., Kim, Z.A. Munir, “Synthesis and consolidation of nanostructured W–10–40wt.% Cu powders,” Materials Science and Engineering: A, Vol.405(1), 325-332, 2005 DOI: https://doi.org/10.1016/j.msea.2005.06.015

[7] M. Amirjan, Z.M.K., N. Parvin, “Evaluation of microstructure and contiguity of W/Cu composites prepared by coated tungsten powders,” International Journal of Refractory Metals and Hard Materials, Vol. 27(4), 729-733, 2009. DOI: https://doi.org/10.1016/j.ijrmhm.2008.12.008

[8] J. Cheng, P. Song, Y. Cai, Y. Xia, “Fabrication and characterization of W-15Cu composite powders by a novel mechano-chemical process,” Materials Science and Engineering: A, Vol. 488(1-2), 453-457, 2008. DOI: https://doi.org/10.1016/j.msea.2007.11.022

[9] A. Mondal, A. Upadhyaya, D. Agrawal, “Comparative study of densification and microstructural development in W18Cu composites using microwave and conventional heating,” Materials Research Innovations,Vol. 14(5), 355-360, 2010. DOI: https://doi.org/10.1179/143307510X12820854748638

[10] Y.D. Kim, N.L. Oh, S.T. Oh, I.H. Moon, “Thermal conductivity of W-Cu composites at various temperatures,” Materials letters, Vol.51(5), 420-424, 2001. DOI: https://doi.org/10.1016/S0167-577X(01)00330-5

[11] J. Johnson, R. German, “Phase equilibria effects on the enhanced liquid phase sintering of tungsten-copper,” Metallurgical and Materials Transactions A, Vol. 24(11), 2369-2377,1993. DOI: https://doi.org/10.1007/BF02646516

[12] Y. Boonyongmaneerat, “Effects of low-content activators on low-temperature sintering of tungsten,” Journal of Materials Processing Technology, Vol. 209(8) 4084-4087 ,2009 DOI: https://doi.org/10.1016/j.jmatprotec.2008.09.026

[13] R. German, ZA. Munir, “Enhanced low-temperature sintering of tungsten,” Metallurgical and Materials Transactions A, Vol.7(11), 1873-1877, 1976. DOI: https://doi.org/10.1007/BF02654983

[14] I. Hafed, A. Azizan, R. Azmi. “Effects of cobalt addition and temperature on microstructure and density of W-25Cu composites prepared via liquid infiltration,” Advanced Materials Research, Vol.626, 430-435, 2013 DOI: https://doi.org/10.4028/www.scientific.net/AMR.626.430

[15] S.H. Hong, B.K. Kim, Z.A. Munir, “Fabrication of W-20 wt% Cu composite nanopowder and sintered alloy with high thermal conductivity,” Materials letters, Vol. 57(18), 2761-2767,2003 DOI: https://doi.org/10.1016/S0167-577X(03)00071-5

[16] M. Ardestani, HR Rezaie, H. Arabi, H. Razavizadeh, “The effect of sintering temperature on densification of nanoscale dispersed W–20–40% wt. Cu composite powders,” International Journal of Refractory Metals and Hard Materials, Vol. 27(5), 862-867, 2009. DOI: https://doi.org/10.1016/j.ijrmhm.2009.04.004

[17] M. Ahangarkani, S. Borgi, H. Abbaszadeh, A. A. Rahmani, K. Zangeneh-Madar, “The effect of additive and sintering mechanism on the microstructural characteristics of W–40Cu composites”. International Journal of Refractory Metals and Hard Materials, Vol.32, 39-44, 2012. DOI: https://doi.org/10.1016/j.ijrmhm.2012.01.006

[18] K. Daneshjou, M. Ahmadi, “Optimizing the effective parameters of tungsten- copper composites,” Transactions of the Canadian Society for Mechanical Engineering, Vol. 30(3), 321-328, 2006. DOI: https://doi.org/10.1139/tcsme-2006-0020

[19] K.S. Mohammad, A. Rahmat, A.B. Ismail, “The effects of Fe additions on the liquid phase sintering of W–bronze composites,” Journal of Alloys and Compounds, Vol.482(1), 447-454, 2009. DOI: https://doi.org/10.1016/j.jallcom.2009.04.061

[20] H. Ibrahim, A. Aziz, and A. Rahmat, “Enhanced liquid-phase sintering of W–Cu composites by liquid infiltration,” International Journal of Refractory Metals and Hard Materials, Vol.43, 222-226, 2014 DOI: https://doi.org/10.1016/j.ijrmhm.2013.12.004

[21] H. Zhang, J. R. Liu, G. H. Zhang, “Preparation and properties of W-30 wt% Cu alloy with the additions of Ni and Fe elements,” Journal of Alloys and Compounds, Vol.928, 167040, 2022 DOI: https://doi.org/10.1016/j.jallcom.2022.167040

[22] H. Zhang, X. C. Deng, G. H. Zhang, “Preparation and properties of multiphase solid-solution strengthened high-performance W–Cu alloys through alloying with Mo, Fe and Ni,” Materials Science and Engineering: A, Vol 871, 144909, 2023. DOI: https://doi.org/10.1016/j.msea.2023.144909

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Published

2024-09-30

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How to Cite

The Effect of Co and Fe on Densification and Microstructure of W- 25wt%Cu Composites Prepared by Direct Liquid Infiltration. (2024). Derna University Journal of Applied Sciences, 1(1), 10-16. https://doi.org/10.58987/pg1j4c55

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